This cache is the 8th in a series of 22 hides to be named after
chemical elements and placed on Ramsey streets (and sometimes
points North) with the same name. The series will speed up the
qualification requirements for challenge cache
GC2P5TJ, since some already published elements
require traveling great distances. The closest cache named
Sodium is located in North Carolina, 852 miles
Southeast.
History: Until the 18th century no distinction
was made between potassium and sodium. This was because early
chemists did not recognise that "vegetable alkali"
(K2CO3, potassium carbonate, coming from
deposits in the earth) and "mineral alkali"
(Na2CO3, sodium carbonate, derived from wood
ashes) are distinct from each other. Eventually a distinction was
made.
Sodium was first isolated in 1807 by Sir Humphry Davy, who made
it by the electrolysis of very dry molten sodium hydroxide, NaOH.
Sodium collected at the cathode. Davy isolated potassium by a
similar procedure, also in 1807. Shortly after, Thenard and
Gay-Lussac isolated sodium by reducing sodium hydroxide with iron
metal at high temperatures.
Sodium is one of the elements which has an alchemical symbol,
shown below (alchemy is an ancient pursuit concerned with, for
instance, the transformation of other metals into gold).
Sources: Sodium is never found as the free
element ("native") in nature as it is so reactive. Sodium is the
sixth most abundant element in the earth's crust at about 2.6 -
3.0%. The most common mineral is rock salt (sodium chloride, NaCl,
or halite), but it occurs in many other minerals including sodium
borate (borax), sodium carbonate (soda), sodium nitrate (Chile
saltpetre). and sodium sulphate (thenardite). In those species,
however, it is the anions that are the reason for mining.
Uses:
- sodium metal is used in the preparation of tetraethyl lead,
PbEt4, an important anti-knock reagent in leaded petrol
(gasoline) - fortunately being phased out in many countries because
of lead pollution problems
- sodium metal is used in the preparation of titanium metal from
TiCl4
- the metal is used in the manufacture of sodamide, sodium
cyanide, sodium peroxide, and sodium hydride
- the metal is used in the reduction of organic esters, and in
the preparation of organic compounds
- the alloy with potassium, NaK, is an important heat transfer
agent and a good chemical reducing agent (as some proportions of Na
and K are liquid at room temperature).
- sodium compounds including "common salt" (sodium chloride,
NaCl), "soda ash" (sodium carbonate, Na2CO3),
"baking soda" (sodium bicarbonate, NaHCO3, "bicarb"),
and "caustic soda" (sodium hydroxide, NaOH), are important to the
paper, glass, soap, textile, petroleum, chemical, and metal
industries
- sodium vapour is used in lamps for street lighting
- table salt - don't use too much!