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Don't Cache on Fire Mystery Cache

This cache has been archived.

Keystone: As the owner has not responded to my prior note, I am archiving this listing.

Keystone
Geocaching.com Volunteer Cache Reviewer

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Hidden : 6/6/2007
Difficulty:
3 out of 5
Terrain:
1.5 out of 5

Size: Size:   micro (micro)

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Geocache Description:

A quick, rather unglamourous park-and-grab on the University of Pittsburgh campus with a nice place to sit and enjoy some time and snap your picture with the Cathedral of Learning nearby. The difficulty rating is mostly for the puzzle, although the current hide I'd now rate as a 2. The current incarnation of the cache is a camouflaged Altoids candy tin and until I can get a larger container/better spot this may be more about the puzzle than an interesting find. BYOP!


The cache is not at the coordinates listed. To find the actual coordinates you’ll have to do a little high school chemistry.

The coordinates given will take you to the front doors of the Department of Chemistry's Chevron Science Center on the University of Pittsburgh campus. Long, long ago, not far away from these doors I was in an accident here when there was a sodium fire that ended up igniting some nearby isopropanol and acetone (two things you very likely have in your home as they’re very useful solvents - check your rubbing alcohol and nail polish remover) and then my leg!


Do some chemistry...

The reactions that took place that day are examples of combustion reactions. In the most common examples, a fuel is combined with oxygen which will react to give off heat and water and carbon dioxide if an ignition source is present.

Below are representations of four organic compounds that can undergo combustion reactions. The reactions of the first two you may encounter on a daily basis. The latter two are acetone and isopropanol that were mentioned above.

To find the cache coordinates you will have to balance the four combustion reactions of these compounds in a pure oxygen environment and answer the question. This is basic general chemistry so don't scare off too easily now.

Balance these four equations finding the values of A thru S...

A nicotine + B oxygen C carbon dioxide + D water + E nitrogen
F ethanol + G oxygen H carbon dioxide + I water
K acetone + L oxygen M carbon dioxide + N water
O isopropanol + P oxygen R carbon dioxide + S water

Now try a little stoichiometric problem - How many milligrams of oxygen are needed to complete the reaction of 0.178 grams of nicotine (about 20 cigarette's worth)? Format answer as TUV mg.

The final coordinates are N 40° 26.SKF' W 079° 57.TUV'. The verification allows for rounding differences in the west coordinate.

Click to verify coordinates


Find the cache...

With the coordinates in hand you should be able to find the cache easily as long as the muggles aren't too plentiful. The view of the Cathedral of Learning isn't as great as the old location...but you can still see it!

The cache container is a camo'd altoids candy tin in its current incarnation. Please make sure when you are finished that it is sealed tighly and hidden better than you found it. (There is a restroom inside the nearby building inside the front doors and to your right if you need to wash your hands.)

Please keep your senses about you as you hunt the cache. I would recommend taking a buddy with you if you like to cache late at night.

The initial contents included: the newly released G.N. Lewis Nanomole Travelbug (TB1CPKK), two containers of Play-doh, and a toy bear, bird, and starfish...all made of polymers! $5 in Rita's Italian Ice gift certificates are tucked away in the logbook for the first-to-find as a way to cool down after your hard work finding this cache or others this summer.

Please let me know if you think this was easier or harder than the rating I've set. I do these types of problems several times a day and so admittedly have lost touch! Thanks!


Additional Hints (Decrypt)

fgnl ng rlr yriry naq ernyvmr n fznyy fvmr pnpur znl tb urer va gur shgher

Decryption Key

A|B|C|D|E|F|G|H|I|J|K|L|M
-------------------------
N|O|P|Q|R|S|T|U|V|W|X|Y|Z

(letter above equals below, and vice versa)