Skip to content

Liesegang Bands ~ Hard Rock or Golden Oldies? EarthCache

Hidden : 6/18/2010
Difficulty:
2 out of 5
Terrain:
2 out of 5

Size: Size:   not chosen (not chosen)

Join now to view geocache location details. It's free!

Watch

How Geocaching Works

Please note Use of geocaching.com services is subject to the terms and conditions in our disclaimer.

Geocache Description:


Welcome to the next edition of Doc.’s Roadside Geology Tour: Jackson County!


As we wind our way down and around “The Road Less Traveled” in the back hills of Jackson County, Hollywood’s greatest secret is about to be exposed….!

Behold! .....The secret origins of the Yellow Brick Road! Flying monkeys and errant ruby slippers have been sighted within this quadrant of the Driftless Zone ….. Oh My!!!!!


The above listed coordinates will bring you to a brilliant roadcut in this little sector of the “Driftless Zone” which exposes the sedimentary history and the beauty of the Cambrian sandstone that underlies the steep hills and coulees of the region. This region narrowly escaped the deleterious effects of the last glacial advance by several miles, but now tells us what’s in those outlying mounds we just passed through.

The purpose of this EarthCache is to allow you the opportunity to get up close and personal with the geology at this site.

First, you are looking at an exposed section of a lower deposition of the Wonewoc Formation. There are no fossils in this formation as opposed to the prior deposition of the Eau Claire formation which hosts early marine invertebrate fossils such as trilobites, brachiopods, crinoids, hyoliths, etc.

Take some time to examine the texture and integrity of the sandstone wall. Feel and observe the hardness of the rock wall, the differences in hardness of the brilliant orange sandstone vs. the lighter or white sandstone. Also note the size and texture of the sand granules, both in the wall of the roadcut and the eroded sand on the ground. The cohesive “cementing material” creating the rock (or stone) has oxidized and is no longer able to provide the cohesive support for the individual sand grandules.

As you touch and feel the differences between the sandstone of the roadcut vs. the sand washed down from the eroding/oxidizing sandstone wall, please visualize the Table Rock succumbing to the same erosive forces and the dissolution of that fragile structure with time.

Yes, there will be a test!

The path of the Yellow Brick Road is neither straight nor easy. It is known for the tortuous bends and curves…. Just like all those really dark brown hard twisty layers found throughout this sandstone formation. These are known as Liesegang Bands.

The hard, dark brown, curved to irregular bands you are seeing in the road cut rock are deposits of iron minerals and are called Liesegang bands. These bands are reddish-brown to yellow in color and are common in cliff-forming sandstones. Much of the red iron mineralization in these bands are hematite, goethite and limonite. The source of the iron is the carbonate mineral siderite. But when siderite weathers, it oxidizes forming the yellow-brown mineral limonite as well as hematite and goethite. Rainwater penetrated the rock and oxidized the pyrite to form liesegang bands of red hematite (Fe2O3) and orange and brown goethite (FeO(OH)).

Liesegang bands are poorly understood chemical structures often seen in rocks, especially sandstones. They were discovered more than a hundred years ago by the German chemist Raphael E. Liesegang, when he accidentally dropped a drop of silver nitrate solution on a layer of gel containing potassium dichromate, and concentric rings of silver dichromate started to form.

In sedimentary rocks, Liesegang bands appear well after the sediment has become a rock (that is, it got compacted and cemented). Stratification and lamination within the sansdtone are typically cross-cut by the Liesegang bands; fractures usually have a more obvious effect on the distribution and orientation of these.

To claim credit for this EarthCache, please email to me:

1. Do you see a pattern to the deposition of the iron oxide banding in the road cut face?
2. How thick is the largest liesegang band in the road cut?
3. Is the liesegang band harder or softer than the surrounding sandstone wall?
4. Please post a picture to document your visit to this site.

Don’t forget to buckle up for your next stop on Doc.’s Roadside Tour of Jackson County.

Additional Hints (No hints available.)