Please see:
Bond 01 - Dr. No
for a list of caches in the series.
Movie #: 02
Title: From Russia With Love
Year: 1963
Bond: Sean Connery
Villain: Rosa Klebb, SMERSH #3 (Lotte Lenya)
Woman: Tanya (Daniela Bianchi)
Song: From Russia With Love, performed by Matt Monro
Memorable gadget: Bond's exploding briefcase.
Memorable quote: Tanya: That horrible woman. Bond: Yes, she's had her kicks (after Klebb fights Bond with a poison knife in her shoe).
Memorable stunt: Bond and Tanya filmed behind a 2-way mirror for blackmail.