From Russia with love
Released in 1963 and again starring Sean Connery as James Bond. Two notable baddies in the film were Grant played by Robert Shaw and Rosa Klebb ( she of the incredible poison tipped shoe) played by Lotte Lenya. The budget for the film was estimated at $2,000,000 and grossed $78,900,000 Worldwide.
Interesting fact; First Bond film to end with the declaration "James Bond will return in ...", in this case it was Goldfingerf (1964). A tradition that would continue until it was used for the last time at the end of Octopussy (1983).