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Ruthenium is a chemical element with the symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemicals. Russian-born scientist of Baltic-German ancestry Karl Ernst Claus discovered the element in 1844 at Kazan State University and named ruthenium in honor of Russia. Ruthenium is usually found as a minor component of platinum ores; the annual production has risen from about 19 tonnes in 2009 to some 35.5 tonnes in 2017. Most ruthenium produced is used in wear-resistant electrical contacts and thick-film resistors. A minor application for ruthenium is in platinum alloys and as a chemistry catalyst. A new application of ruthenium is as the capping layer for extreme ultraviolet photomasks. Ruthenium is generally found in ores with the other platinum group metals in the Ural Mountains and in North and South America.
As the 78th most abundant element in Earth's crust, ruthenium is relatively rare, found in about 100 parts per trillion. This element is generally found in ores with the other platinum group metals in the Ural Mountains and in North and South America. Small but commercially important quantities are also found in pentlandite extracted from Sudbury, Ontario, Canada, and in pyroxenite deposits in South Africa. The native form of ruthenium is a very rare mineral (Ir replaces part of Ru in its structure). Ruthenium has a relatively high fission product yield in nuclear fission and given that its most long lived radioisotope has a half life of "only" around a year, there are often proposals to recover ruthenium in a new kind of nuclear reprocessing from spent fuel. An unusual ruthenium deposit can also be found at the natural nuclear fission reactor that was active in Oklo, Gabon some two billion years ago. Indeed, the isotope ratio of ruthenium found there was one of several ways used to confirm that a nuclear fission chain reaction had indeed occurred at that site in the geological past. Uranium is no longer mined at Oklo and there have never been serious attempts to recover any of the platinum group metals present there. Roughly 30 tonnes of ruthenium are mined each year with world reserves estimated at 5,000 tonnes. Ruthenium, like the other platinum group metals, is obtained commercially as a by-product from nickel, and copper, and platinum metals ore processing. During electrorefining of copper and nickel, noble metals such as silver, gold, and the platinum group metals precipitate as anode mud, the feedstock for the extraction.
ruthenium ore
Though naturally occurring platinum alloys containing all six platinum-group metals were used for a long time by pre-Columbian Americans and known as a material to European chemists from the mid-16th century, not until the mid-18th century was platinum identified as a pure element. That natural platinum contained palladium, rhodium, osmium and iridium was discovered in the first decade of the 19th century. Platinum in alluvial sands of Russian rivers gave access to raw material for use in plates and medals and for the minting of ruble coins, starting in 1828. Residues from platinum production for coinage were available in the Russian Empire, and therefore most of the research on them was done in Eastern Europe.
It is possible that the Polish chemist Jędrzej Śniadecki isolated element 44 (which he called "vestium" after the asteroid Vesta discovered shortly before) from South American platinum ores in 1807. He published an announcement of his discovery in 1808. His work was never confirmed, however, and he later withdrew his claim of discovery.
Jöns Berzelius and Gottfried Osann nearly discovered ruthenium in 1827. They examined residues that were left after dissolving crude platinum from the Ural Mountains in aqua regia. Berzelius did not find any unusual metals, but Osann thought he found three new metals, which he called pluranium, ruthenium, and polinium. This discrepancy led to a long-standing controversy between Berzelius and Osann about the composition of the residues. As Osann was not able to repeat his isolation of ruthenium, he eventually relinquished his claims. The name "ruthenium" was chosen by Osann because the analysed samples stemmed from the Ural Mountains in Russia. The name itself derives from the Latin word Ruthenia; this word was used at the time as the Latin name for Russia.
Karl Ernst Claus
In 1844, Karl Ernst Claus, a Russian scientist of Baltic German descent, showed that the compounds prepared by Gottfried Osann contained small amounts of ruthenium, which Claus had discovered the same year. Claus isolated ruthenium from the platinum residues of rouble production while he was working in Kazan University, Kazan, the same way its heavier congener osmium had been discovered four decades earlier. Claus showed that ruthenium oxide contained a new metal and obtained 6 grams of ruthenium from the part of crude platinum that is insoluble in aqua regia. Choosing the name for the new element, Claus stated: "I named the new body, in honour of my Motherland, ruthenium. I had every right to call it by this name because Mr. Osann relinquished his ruthenium and the word does not yet exist in chemistry." In doing so, Claus started a trend that continues to this day - naming an element after a country.