Bohrium is a chemical element with the symbol Bh and atomic
number 107 and is the heaviest member of group 7 (VIIB). It is a
synthetic element whose most stable known isotope,
270Bh, has a half-life of 61 seconds. Chemical
experiments have confirmed bohrium's predicted position as a
heavier homologue to rhenium with the formation of a stable +7
oxidation state.
The first convincing synthesis was in 1981 by a German research
team led by Peter Armbruster and Gottfried Münzenberg at the
Gesellschaft für Schwerionenforschung (Institute for Heavy Ion
Research, GSI) in Darmstadt using the Dubna reaction.
In 1989, the GSI team successfully repeated the reaction during
their efforts to measure an excitation function. During these
experiments, 261Bh was also identified in the 2n
evaporation channel and it was confirmed that ,262Bh
exists as two states - a ground state and an isomeric state. The
IUPAC/IUPAP Transfermium Working Group (TWG) report in 1992
officially recognized the GSI team as discoverers of element
107.
Historically element 107 has been referred to as eka-rhenium.
The German group suggested the name nielsbohrium with symbol Ns to
honor the Danish physicist Niels Bohr. The Soviet scientists had
suggested this name be given to element 105 (which was finally
called dubnium) and the German team wished to recognize both Bohr
and the fact that the Dubna team had been the first to propose the
cold fusion reaction. There was an element naming controversy as to
what the elements from 104 to 106 were to be called; the IUPAC
adopted unnilseptium (symbol Uns) as a temporary, systematic
element name for this element. In 1994 a committee of IUPAC
rejected the name nielsbohrium since there was no precedence for
using a scientist's complete name in the naming of an element and
thus recommended that element 107 be named bohrium. This was
opposed by the discoverers who were adamant that they had the right
to name the element. The matter was handed to the Danish branch of
IUPAC who voted in favor of the name bohrium. There was some
concern however that the name might be confused with boron and in
particular the distinguishing of the names of their respective
oxo-ions bohrate and borate. Despite this, the name bohrium for
element 107 was recognized internationally in 1997. The IUPAC
subsequently decided that bohrium salts should be called
bohriates.